They started equal. Martha spent $21 more than Mary ($36 vs $15), so after spending Mary has $21 more than Martha. Mary now = 2 units, Martha now = 1 unit, so that extra unit is the $21.
Plain numbers are given; italic underlined numbers are worked out.
Extra spent by Martha → $36 − $15 = $21
Mary − Martha now = 1 unit → $21 (so Martha now = $21, Mary now = $42)
Mary at first → $42 + $15 = $57
Both started equal → total = 2 × $57 = $114
They had $114 altogether at first.
Check: each $57; Mary $57−$15=$42, Martha $57−$36=$21, and $42 = 2 × $21. ✓
Alternative method (algebra)
Let each start with $m. Mary: m − 15; Martha: m − 36.